Multidimensional Ni-Co-sulfide heterojunction electrocatalyst for highly efficient overall water splitting

نویسندگان

چکیده

Heterostructure engineering holds exceptional promise for the development of high-performance electrocatalysts overall water splitting. However, production inexpensive and high-efficiency bifunctional remains a challenge. Herein, we demonstrate simple method to synthesize paper-mulberry (Broussonetia papyrifera)-in-spired Co9S8@CoNi2S4/nickel foam (Co9S8@CoNi2S4/NF) heterojunction with high catalytic activity stability. The process involves in situ growth NiCo layered double hydroxide derivatization ZIF-67, followed by S heteroatom doping. Co9S8@CoNi2S4/NF benefits from heterostructure functional advantages multidimensional building blocks including one-dimensional (1D) nanowires, 2D nanosheets nanoparticles. optimized 10% sulphur content reveals excellent electrocatalytic lower over-potentials 68 mV hydrogen evolution reaction (HER) 170 oxygen (OER) at 10 mA cm?2 1.0 mol L?1 KOH solution, which is superior recently reported transition metal based electrocatalysts. outstanding performance attributed strong interface coupling between CoNi2S4 Co9S8, advantage structure customized electronic structure. density theory suggests that Co9S8 optimizes adsorption multiple intermediates further facilitates splitting kinetics. This work offers generic approach design system applications.

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ژورنال

عنوان ژورنال: Science China. Materials

سال: 2022

ISSN: ['2095-8226', '2199-4501']

DOI: https://doi.org/10.1007/s40843-021-1994-8